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-o. lawesson by heating ethyl -acylaminobenzoates, , with the dimer of p-methoxy-phenylthionophosphine sulfide, , at °c a mixture of ethyl -thioacylamino-benzoates, , -substituted , -benzothiazin- -ones, , and -substituted , -benzothiazine- -thiones, , is obtained. by raising the reaction temperature...
https://www.researchgate.net/publication/230327710_Studies_on_organophosphorus_compounds_XXIII_synthesis_of_salicylthioamides_and_4H-132-benzoxaphoshorine_derivatives_from_the_dimer_of_p-methoxyphenylthionophosphine_sulfide_and_salicylamides