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naturally forms in starchy food products during every-day high- temperature cooking (at above 120degc and low-moisture), due to a reaction between sugars and amino acids naturally present in many foods. this is known as the maillard reaction that also 'browns' food and affects its taste. acrylamide is not
added to food, but naturally forms in a wide range of products, such as bread, biscuits, breakfast cereals, potato crisps, french fries and coffee, whether they are cooked at home, in restaurants or commercially. even though scientists only discovered it in food in 2002, it has actually been present...
http://www.ceereal.eu/images/technical-docs/Statement_on_Acrylamide_in_Breakfast_Cereals_FIN.pdf