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a sulfhydryl group (-sh), a reactive thiol crucial for the role played by the coenzyme, because the acyl groups bonded to it through a thioester bond have a high standard free energy of hydrolysis. this provides acyl groups with a high transfer potential, equal to kcal/mol ( kj/mol), slightly more exergonic...
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, and can also function as an autocrine signal . depending on cell type, it can drive adaptive/developmental changes requiring protein synthesis . in smooth muscle , cgmp is the signal for relaxation, and is coupled to many homeostatic mechanisms including regulation of vasodilation , vocal tone, insulin...